Preparation, spectroscopic and structural characterization of η1-N and η2-Se,Se′ complexes of a P2N4Se2 ring - MacEwan Users Only

Chivers, T., Doxsee, D. D., Hilts, R., Meetsma, A., Parvez, M., & Grampel, J. C. van de. (1992). Preparation, spectroscopic and structural characterization of η1-N and η2-Se,Se′ complexes of a P2N4Se2 ring.
Metadata
TitlePreparation, spectroscopic and structural characterization of η1-N and η2-Se,Se′ complexes of a P2N4Se2 ring
Author(s)Chivers, Tristram; Doxsee, Daniel D.; Hilts, Robert; Meetsma, Auke; Parvez, Masood; Grampel, Johan C. van de
Date1992
Keyword(s)x-ray structure, crystal-structures, Se4N4
DescriptionThe reaction of 1,5-Ph4P2N4Se2, 1, prepared by the treatment of Ph2PN2(SiMe3)3 with a mixture of SeCl4 and Se2Cl2 in acetonitrile, with [PtCl2(PEt3)]2 gives the adducts [PtCl2(PEt3)]n[η1-N-Ph4P2N4Se2](2, n- 1; 3, n- 2) in which the P2N4Se2 ring is shown by an X-ray structural determination of 3 to contain a transannular Se–Se interaction; the oxidative addition of 1 or 2 to Pt(C2H4)(PPh3)2 produces the corresponding η2-Se,Se′ complexes.
Peer ReviewedYes
Type of ItemJournal Articles
MacEwan Users Onlyhttp://library.macewan.ca/cgi-bin/SFX/url.pl/7OY
LanguageEnglish
RightsAll Rights Reserved