Formation, x-ray structure, and deprotonation of an S,S'-methylene-bridged P2N4S2 ring - MacEwan Users Only

Chivers, T., Cowie, M., Edwards, M., & Hilts, R. (1992). Formation, x-ray structure, and deprotonation of an S,S'-methylene-bridged P2N4S2 ring.
Metadata
TitleFormation, x-ray structure, and deprotonation of an S,S'-methylene-bridged P2N4S2 ring
Author(s)Chivers, Tristram; Cowie, Martin; Edwards, Mark; Hilts, Robert
Date1992
Keyword(s)sulfur nitrogen ligands, complexes, disulfides, anions, inorganic and nuclear chemistry
DescriptionThere is an extensive chemistry of binary sulfur-nitrogen (S- N) anions, several of which are shown only in coordination complexes with metals. Although there is polarographic evidence for the formation of S4N4(2-) at low temperatures, this dianion has only been characterized in Ira and Pt5b complexes as a tridentate (N,S,S’) ligand formed by insertion of the metal into an S-N bond of S4N4. Anions of diphosphadithiatetrazocines 1 are unknown, but Pt0 or Pd0 compounds readily undergo oxidative addition with these norganic heterocycles to give ŋ2- S4ZS1-metal complexes.(6)
Peer ReviewedYes
Type of ItemJournal Articles
MacEwan Users Onlyhttps://library.macewan.ca/cgi-bin/SFX/url.pl/7PE
LanguageEnglish
RightsAll Rights Reserved