Browsing by Author "Atienza, Bren Jordan"
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Item Azide trapping of metallocarbenes: generation of reactive C-acylimines and domino trapping with nucleophiles(2014) Bott, Tina; Atienza, Bren Jordan; West, F. G.Azide-tethered diazocarbonyl compounds undergo copper-catalyzed conversion to transient C-acylimines. These reactive intermediates can be trapped with a variety of carbon nucleophiles, giving rise to complex 3-indolinone frameworks, including those with adjacent tetra-substituted carbon centers, in a single transformation.