Browsing by Author "Poole, Hailey"
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Item Use of a switchable-hydrophilicity solvent as both a solvent and a catalyst in aldol condensation(2019) Poole, Hailey; Gauthier, Jeremy; Vanderveen, Jesse R.; Jessop, Philip G.; Lee, RolandA switchable-hydrophilicity solvent, N,N-dimethylcyclohexylamine, was used as a recyclable catalyst and solvent for aldol condensation, giving >97% pure product in 94% isolated yield without the need for purification or additional solvents. CO2-triggered separation produced yields greater than conventional workup and allowed facile recycling of the amine.