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Azide trapping of metallocarbenes: generation of reactive C-acylimines and domino trapping with nucleophiles

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dc.contributor.authorBott, Tina
dc.contributor.authorAtienza, Bren Jordan
dc.contributor.authorWest, F. G.
dc.date.accessioned2021-05-17
dc.date.accessioned2022-05-31T01:43:38Z
dc.date.available2022-05-31T01:43:38Z
dc.date.issued2014
dc.description.abstractAzide-tethered diazocarbonyl compounds undergo copper-catalyzed conversion to transient C-acylimines. These reactive intermediates can be trapped with a variety of carbon nucleophiles, giving rise to complex 3-indolinone frameworks, including those with adjacent tetra-substituted carbon centers, in a single transformation.
dc.format.extent514.16KB
dc.format.mimetypePDF
dc.identifier.citationBott, T. M., Atienza, B. J., West, F. G. Azide. (2014). Azide trapping of metallocarbenes: generation of reactive C-acylimines and domino trapping with nucleophiles.RSC Advances, 4(60), 31955-31959. https://doi.org/10.1039/C4RA06044J
dc.identifier.doihttps://doi.org/10.1039/C4RA06044J
dc.identifier.urihttps://hdl.handle.net/20.500.14078/2277
dc.languageEnglish
dc.language.isoen
dc.rightsAll Rights Reserved
dc.subjectazide-tethered diazocarbonyl
dc.subjectC-acylimines
dc.subjectnitrogen heterocycles
dc.subjecttertiary amine
dc.subjectcarbonyl ylides
dc.subjectSchmidt rearrangement
dc.subjectaziridination of electron-deficient alkenes
dc.subjectdinitrogen
dc.subjectbetaine
dc.subjectnucleophile
dc.titleAzide trapping of metallocarbenes: generation of reactive C-acylimines and domino trapping with nucleophilesen
dc.typeArticle

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