Department of Physical Sciences
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Item Research recast(ed): S3E15 - Creative chemists on creating a cleaner, greener future for everyone(2024) Leschyshyn, Brooklyn; Smadis, Natalie; Lee, Roland; Mundle, TrevorOn today’s episode we had the pleasure of being joined by Dr. Roland Lee and Trevor Mundle. The two test our preconceived notion of the truth behind environmentally friendly products. Dr. Roland Lee and Trevor Mundle collaborate between the MacEwan lab and Green Tech, bringing together experts in chemistry, finance, investment, and sustainable practices. They use cutting-edge pyrolysis technology to convert various feedstocks into valuable products, which reduces emissions, fossil fuel dependencies, water usage, and landfill needs. Their objective is to transform waste streams into valuable resources.Item Research recast(ed): S3E3 - Bringing young minds to MacEwan through experiences, experiments, and fun with Dr. Emily Milne, Dr. Kaitlyn Towle, and Steven Campbell(2023) Leschyshyn, Brooklyn; Smadis, Natalie; Milne, Emily; Towle, Kaitlyn; Campbell, StevenOn today’s episode, we talk to Dr. Emily Milne, Kaitlyn Towle, and Steven Cambell about MacEwanCYU. With the help of MacEwan, students from Ben Calf Robe can learn about what the university has to offer. Their project helps to inspire young minds and invite them to aspire to a secondary education.Item Research recast(ed): MacEwan Celebrates Month of Scholarship - Dr. Erin Walton(2022) Ekelund, Brittany; Cave, Dylan; Walton, ErinToday’s episode is literally out of this world as we talk about meteorites, asteroids and moon rocks with geologist Dr. Erin Walton, an associate professor in the Department of Physical Sciences at MacEwan University, whose primary research focuses on shock metamorphism recorded in martian meteorites. Along the way, we’ll discuss mentorship, space colonization and the economic benefit of finding impact craters. We will also get a glimpse into Dr. Walton’s new exciting avenue of research into her all-time favorite asteroid, 4-Vesta.Item Research recast(ed): MacEwan celebrates month of scholarship - Dr. Samuel Mugo(2022) Ekelund, Brittany; Cave, Dylan; Mugo, SamuelToday we learn about smart technology and the democratization of health through point-of-need sensors with Dr. Samuel Mugo, a professor of analytical chemistry at MacEwan University, whose research program involves the use of smart sensor technology for human and animal health and wellness, as well as agri-food chemical analysis. Along the way, we will learn about the United Nations Sustainable Development goals, and find out how chemistry and technology can come together to address food security and help people take control of their physical and mental wellness.Item Using GIS and remote sensing to monitor industrial impacts to archaeological sites in the Athabasca Oil Sands of Alberta(2021) Wadsworth, William T. D.; Dersch, Ave; Woywitka, Robin; Supernant, KishaThe Athabasca Oil Sands (AOS) region of Alberta has one of the densest accumulations of known archaeological sites, and possibly the most archaeological sites at risk, in the country. Expanding industrial development has been a characteristic of this region for decades, and as a result, abundant archaeological work has been done and regulatory requirements put in place to mitigate site disturbance. Until recently, there has been little quantitative evidence to assess human impact on archaeological resources in the region. The goal of this paper is to raise awareness of the critical need to incorporate new archaeological remote sensing strategies to improve site monitoring approaches. We present methods and results from our GIS-based analysis that seeks to locate and partially characterize impacted sites. We argue that combining publicly accessible remote sensing products with geospatial archaeological site information allows for better documenting and monitoring of industry impacts in the AOS. We show that 43% of all sites sampled (n=1943) are disturbed. Of these sites, 160 were potentially affected by Historical Resources Act non-compliant impacts (including five HRV 1 sites). We contextualize our results within current systemic challenges and we recommend the incorporation of community monitoring programs to ground-truth similar GIS analyses and increase our ability to effectively monitor industrial impacts to archaeological sites.Item Topographic setting of archaeological survey in the Boreal Forest of Alberta(2021) Woywitka, Robin; Michalchuk, BenjaminThe archaeological record of the Canadian Boreal Forest is dominated by shallowly buried sites with little to no datable artifacts or stratigraphy. This has led to characterizations of the region as an area of low scientific interpretive value. However, the factors that underlie this skew to shallow sites are rarely formally examined. Here we use a geomorphon-based terrain classification to assess the role of topographic setting in the placement of archaeological survey points. Our results show that there is considerable bias in current archaeological survey methods towards landforms that disperse sediment. This reduces the likelihood of finding deeply buried or stratified sites and calls into question the assertion that datable sites are largely absent from the region. We recommend that increased sampling of low-lying terrain should be a regular component of Boreal Forest survey methodology.Item Late Pleistocene and Early Holocene obsidian in Alberta and human dispersal into North America’s ice-free corridor(2023) Kristensen, Todd; Allan, Timothy E.; Ives, John W.; Woywitka, Robin; Yanicki, Gabriel; Rasic, Jeffrey T.We utilize pXRF to source the oldest obsidian artifacts in Alberta, Canada. The province lacks obsidian outcrops and hosts much of the late Pleistocene Ice-Free Corridor, the northern and southern ends of which are in proximity to obsidian outcrops in Yukon, Alaska, Idaho, and Wyoming. The early presence of these obsidians in Alberta informs models of human dispersion. Results point to an early establishment of relationships in the central Ice-Free Corridor that reached into Oregon, Idaho, and Alaska. Alberta appears to have been entered by people from the south who had ties to the Pacific Northwest and Intermountain West. After biotic viability of a full Corridor, limited evidence suggests that northern people from Beringia may have trickled south and admixed with southern populations in the central Corridor region. Upon deglaciation of access routes through the Rocky Mountains, obsidian from western sources in British Columbia arrived relatively quickly in northern Alberta.Item Lead (Pb) sorption to hydrophobic and hydrophilic zeolites in the presence and absence of MTBE(2021) Zhang, Yunhui; Alessi, Daniel S.; Chen, Ning; Luo, Mina; Hao, Weiduo; Alam, Md. Samrat; Flynn, Shannon L.; Kenney, Janice; Konhauser, Kurt O.; Ok, Yong Sik; Al-Tabbaa, AbirThe co-contamination of the environment by metals and organic pollutants is a significant concern, and one such example is lead (Pb) and methyl tert-butyl ether (MTBE) due to their historic use as fuel additives. Clinoptilolite is an abundant and efficient zeolite for metal removal, but the potential interference of co-existing organic pollutants on metal removal, such as MTBE, have rarely been discussed. In this study, a combination of batch sorption tests and synchrotron-based X-ray absorption spectroscopic analyses were employed to investigate Pb sorption mechanism(s) onto clinoptilolite in the presence and absence of MTBE. A comparison was made to synthetic ZSM-5 zeolite to gain insights into differences in Pb binding mechanisms between hydrophilic (clinoptilolite) and hydrophobic (ZSM-5) zeolites. Site occupancy and surface precipitation contributed equally to Pb removal by clinoptilolite, while surface precipitation was the main Pb removal mechanism for ZSM-5 followed by site occupancy. Despite the negligible effect of 100 mg/L MTBE on observed Pb removal from solution by both zeolites, a surface-embedded Pb removal mechanism, through the Mg site on clinoptilolite surface, arises when MTBE is present. This study provides an understanding of atomic-level Pb uptake mechanisms on zeolites, with and without co-contaminating MTBE, which aids in their application in water treatment at co-contaminated sites.Item Settling behaviors of microplastic disks in water(2023) Yang, Ge; Yu, Zijian; Baki, Abul B. M.; Yao, Weiwei; Ross, Matthew S.; Chi, Wanqing; Zhang, WenmingMicroplastic (MP) disks have not been studied for settling behaviors in aquatic environments, which affects the transport and fate of MPs. Therefore, settling experiments were conducted on MP disks of three shapes and four common-seen materials. Lighter MP disks (with density ρs = 1.038 g/cm3 and length l ≤ 5 mm) followed rectilinear vertical trajectories, while heavier MP disks (ρs = 1.161–1.343 g/cm3 and l = 5 mm) followed zigzag trajectories with oscillations and rotations. The mean terminal settling velocities of MP disks were 19.6–48.8 mm/s. Instantaneous settling velocities of heavier MP disks fluctuated. Existing formulas could not accurately predict the settling velocity of MP disks; thus, a new model was proposed with an error of 15.5 %. Finally, the Red - I* diagram (Red is the disk Reynolds number and I* is the dimensionless moment of inertia) was extended for MP disks to predict settling trajectories.Item Ice, mountains, and people: applying a multi-proxy approach to reveal changes in Alberta’s alpine ecosystems through ice patch research(2023) Tirlea, Diana; Kristensen, Todd; Osicki, Aaron; Jensen, Britta; Williams, Krista; Caners, Richard; Lumley, Lisa; Woywitka, RobinGlacial archaeology has grown and progressed rapidly in recent decades with technological innovations and shifting socio-political issues. However, research on ice patches in the Canadian Rocky Mountains is in its infancy. While Holocene glacial ice retreat, advance, and morphology are well studied in Canada, ice patches in general tend to be understudied because of their limited geomorphological impact on landscapes. This oversight is concerning as their isolated nature, lower elevation, and small mass make ice patches even more susceptible to climate change than glaciers. The importance of documenting these features is heightened by a persisting but tenuous biological importance to a range of modern species. The lack of flow in ice patches also makes them excellent archives of palaeoenvironmental and organic-based cultural materials, as layers of ice and preserved contents are not as distorted as they may be by flow in glaciers.Item Estimated discharge of microplastics via urban stormwater during individual rain events(2023) Ross, Matthew S.; Loutan, Alyssa; Groeneveld, Tianna M.; Molenaar, Danielle; Kroetch, Kimberly; Bujaczek, Taylor; Kolter, Sheldon; Moon, Sarah; Franczak, Brian C.Urban stormwater runoff is an important pathway for the introduction of microplastics and other anthropogenic pollutants into aquatic environments. Highly variable concentrations of microplastics have been reported globally in runoff, but knowledge of key factors within urban environments contributing to this variability remains limited. Furthermore, few studies to date have quantitatively assessed the release of microplastics to receiving waters via runoff. The objectives of this study were to assess the influence of different catchment characteristics on the type and amount of microplastics in runoff and to provide an estimate of the quantity of microplastics discharged during rain events. Stormwater samples were collected during both dry periods (baseflow) and rain events from 15 locations throughout the city of Calgary, Canada’s fourth largest city. These catchments ranged in size and contained different types of predominant land use. Microplastics were found in all samples, with total concentrations ranging from 0.7 to 200.4 pcs/L (mean = 31.9 pcs/L). Fibers were the most prevalent morphology identified (47.7 ± 33.0%), and the greatest percentage of microplastics were found in the 125–250 µm size range (26.6 ± 22.9%) followed by the 37–125 µm size range (24.0 ± 22.3%). Particles were predominantly black (33.5 ± 33.8%), transparent (22.6 ± 31.3%), or blue (16.0 ± 21.6%). Total concentrations, dominant morphologies, and size distributions of microplastics differed between rain events and baseflow, with smaller particles and higher concentrations being found during rain events. Concentrations did not differ significantly amongst catchments with different land use types, but concentrations were positively correlated with maximum runoff flow rate, catchment size, and the percentage of impervious surface area within a catchment. Combining microplastic concentrations with hydrograph data collected during rain events, we estimated that individual outfalls discharged between 1.9 million to 9.6 billion microplastics to receiving waters per rain event. These results provide further evidence that urban stormwater runoff is a significant pathway for the introduction of microplastics into aquatic environments and suggests that mitigation strategies for microplastic pollution should focus on larger urbanized catchments.Item Editorial: multiscale modeling for the liver(2023) Ho, Harvey; Rezania, Vahid; Schwen, Lars OleThe liver is the central metabolic organ in the mammalian body. Hepatic functions need to be understood from a multiscale perspective, i.e., at the organism, organ, lobular, cellular, and molecular levels that can span vastly different timeframes, e.g., from milliseconds of molecular events to months or years of chronic disease formation (cf. Figure 1). Computational models coupled with experimental measurements and clinical observations provide a viable and cost-effective means to investigate hepatic function. The Research Topic collected some recent results, clinical observations, and updated reviews or perspectives; the seven contributions are briefed below.Item Dual continuum upscaling of liver lobule flow and metabolism to the full organ scale(2022) Coombe, Dennis; Rezania, Vahid; Tuszynski, Jack A.The liver is the body’s primary metabolic organ and its functions operate at multiple time and spatial scales. Here we employ multiscale modelling techniques to describe these functions consistently, based on methods originally developed to describe reactive fluid flow processes in naturally-fractured geological sediments. Using a fully discretized idealized lobule model for flow and metabolism, a dual continuum approach is developed in two steps: 1) Two interacting continua models for tissue and sinusoids properties, followed by 2) further upscaled dual continua models leading to an averaged lobule representation. Results (flows, pressures, concentrations, and reactions) from these two approaches are compared with our original model, indicating the equivalences and approximations obtained from this upscaling for flow, diffusion, and reaction parameters. Next, we have generated a gridded dual continuum model of the full liver utilizing an innovative technique, based on published liver outline and vasculature employing a vasculature generation algorithm. The inlet and outlet vasculature systems were grouped into five generations each based on radius size. With a chosen grid size of 1 mm3, our resulting discretized model contains 3,291,430 active grid cells. Of these cells, a fraction is occupied vasculature, while the dominant remaining fraction of grid cells approximates liver lobules. Here the largest generations of vasculature occupy multiple grid cells in cross section and length. The lobule grid cells are represented as a dual continuum of sinusoid vasculature and tissue. This represents the simplest gridded dual continuum representation of the full liver organ. With this basic model, numerous full liver drug metabolism simulations were run. A non-reactive PAC (paclitaxel) injection case including only convective transfer between vasculature and tissue was compared with including an additional diffusive transfer mechanism. These two cases were then rerun with tissue reaction, converting injected PAC to PAC-OH (6-hydroxypaclitaxel). There was little transfer of PAC from vasculature to tissue without the addition of diffusive transfer, and this had a significant observable effect on internal PAC distribution in the absence of reaction, and also on the distribution of PAC-OH for the reactive cases.Item Uranium surface processes with sandstone and volcanic rocks in acidic and alkaline solutions(2023) Kenney, Janice; Lezama-Pacheco, Juan; Fendorf, Scott; Alessi, Daniel S.; Weiss, Dominik J.Understanding the behaviour of uranium waste, for disposal purposes, is crucial due to the correlation between pH values and the disposal of distinct types of waste, with low level waste typically associated with acidic pH values, and higher and intermediate level waste commonly related to alkaline pH values. We studied the adsorption of U(VI) on sandstone and volcanic rock surfaces at pH 5.5 and 11.5 in aqueous solutions with and without bicarbonate (2 mM HCO3–) using XAS and FTIR. In the sandstone system, U(VI) adsorbs as a bidentate complex to Si at pH 5.5 without bicarbonate and as uranyl carbonate species with bicarbonate. At pH 11.5 without bicarbonate, U(VI) adsorbs as monodentate complexes to Si and precipitates as uranophane. With bicarbonate at pH 11.5, U(VI) precipitated as a Na-clarkeite mineral or remained as a uranyl carbonate surface species. In the volcanic rock system, U(VI) adsorbed to Si as an outer sphere complex at pH 5.5, regardless of the presence of bicarbonate. At pH 11.5 without bicarbonate, U(VI) adsorbed as a monodentate complex to one Si atom and precipitated as a Na-clarkeite mineral. With bicarbonate at pH 11.5, U(VI) sorbed as a bidentate carbonate complex to one Si atom. These results provide insight into the behaviour of U(VI) in heterogeneous, real-world systems related to the disposal of radioactive waste.Item Estimated discharge of microplastics via urban stormwater during individual rain events(2023) Ross, Matthew S.; Loutan, Alyssa; Groeneveld, Tianna M.; Molenaar, Danielle; Kroetch, Kimberly; Bujaczek, Taylor; Kolter, Sheldon; Moon, Sarah; Huynh, Alan; Khayam, Rosita; Franczak, Brian C.Urban stormwater runoff is an important pathway for the introduction of microplastics and other anthropogenic pollutants into aquatic environments. Highly variable concentrations of microplastics have been reported globally in runoff, but knowledge of key factors within urban environments contributing to this variability remains limited. Furthermore, few studies to date have quantitatively assessed the release of microplastics to receiving waters via runoff. The objectives of this study were to assess the influence of different catchment characteristics on the type and amount of microplastics in runoff and to provide an estimate of the quantity of microplastics discharged during rain events. Stormwater samples were collected during both dry periods (baseflow) and rain events from 15 locations throughout the city of Calgary, Canada’s fourth largest city.Item A specific dispiropiperazine derivative that arrests cell cycle, induces apoptosis, necrosis and DNA damage(2023) Liu, Victor P.; Li, Wai-Ming; Lofroth, Jack; Zeb, Mehreen; Patrick, Brian O.; Bott, Tina; Lee, Chow H.Dispiropiperazine compounds are a class of molecules known to confer biological activity, but those that have been studied as cell cycle regulators are few in number. Here, we report the characterization and synthesis of two dispiropiperazine derivatives: the previously synthesized spiro[2′,3]- bis(acenaphthene-1′-one)perhydrodipyrrolo-[1,2-a:1,2-d]-pyrazine (SPOPP-3, 1), and its previously undescribed isomer, spiro[2′,5′] bis(acenaphthene-1′-one)perhydrodipyrrolo-[1,2-a:1,2-d]-pyrazine (SPOPP-5, 2). SPOPP-3 (1), but not SPOPP-5 (2), was shown to have anti proliferative activity against a panel of 18 human cancer cell lines with IC50 values ranging from 0.63 to 13 μM. Flow cytometry analysis revealed that SPOPP-3 (1) was able to arrest cell cycle at the G2/M phase in SW480 human cancer cells. Western blot analysis further confirmed the cell cycle arrest is in the M phase. In addition, SPOPP-3 (1) was shown to induce apoptosis, necrosis, and DNA damage as well as disrupt mitotic spindle positioning in SW480 cells. These results warrant further investigation of SPOPP-3 (1) as a novel anti-cancer agent, particularly for its potential ability to sensitize cancer cells for radiation induced cell death, enhance cancer immunotherapy, overcome apoptosis-related drug resistance and for possible use in synthetic lethality cancer treatments.Item Shortwave infrared hyperspectral imaging as a novel method to elucidate multi-phase dolomitization, recrystallization, and cementation in carbonate sedimentary rocks(2021) McCormick, Cole A.; Corlett, Hilary; Stacey, Jack; Hollis, Cathy; Feng, Jilu; Rivard, Benoit; Omma, Jenny E.Carbonate rocks undergo low-temperature, post-depositional changes, including mineral precipitation, dissolution, or recrystallisation (diagenesis). Unravelling the sequence of these events is time-consuming, expensive, and relies on destructive analytical techniques, yet such characterization is essential to understand their post-depositional history for mineral and energy exploitation and carbon storage. Conversely, hyperspectral imaging offers a rapid, non-destructive method to determine mineralogy, while also providing compositional and textural information. It is commonly employed to differentiate lithology, but it has never been used to discern complex diagenetic phases in a largely monomineralic succession. Using spatial-spectral endmember extraction, we explore the efficacy and limitations of hyperspectral imaging to elucidate multi-phase dolomitization and cementation in the Cathedral Formation (Western Canadian Sedimentary Basin). Spectral endmembers include limestone, two replacement dolomite phases, and three saddle dolomite phases. Endmember distributions were mapped using Spectral Angle Mapper, then sampled and analyzed to investigate the controls on their spectral signatures. The absorption-band position of each phase reveals changes in %Ca (molar Ca/(Ca + Mg)) and trace element substitution, whereas the spectral contrast correlates with texture. The ensuing mineral distribution maps provide meter-scale spatial information on the diagenetic history of the succession that can be used independently and to design a rigorous sampling protocol.Item Basin scale evolution of zebra textures in fault-controlled, hydrothermal dolomite bodies: insights from the Western Canadian Sedimentary Basin(2023) McCormick, Cole A.; Corlett, Hilary; Clog, Matthieu; Boyce, Adrian; Tartèse, Romain; Steele-MacInnis, Matthew; Hollis, CathyStructurally controlled dolomitization typically involves the interaction of high-pressure (P), high-temperature (T) fluids with the surrounding host rock. Such reactions are often accompanied by cementation and recrystallization, with the resulting hydrothermal dolomite (HTD) bodies including several ‘diagnostic’ rock textures. Zebra textures, associated with boxwork textures and dolomite breccias, are widely considered to reflect these elevated P/T conditions. Although a range of conceptual models have been proposed to explain the genesis of these rock textures, the processes that control their spatial and temporal evolution are still poorly understood. Through the detailed petrographical and geochemical analysis of HTD bodies, hosted in the Middle Cambrian strata in the Western Canadian Sedimentary Basin, this study demonstrates that a single genetic model cannot be applied to all the characteristics of these rock textures. Instead, a wide array of sedimentological, tectonic and metasomatic processes contribute to their formation; each of which is spatially and temporally variable at the basin scale. Distal to the fluid source, dolomitization is largely stratabound, comprising replacement dolomite, bedding-parallel zebra textures and rare dolomite breccias (non-stratabound, located only proximal to faults). Dolomitization is increasingly non-stratabound with proximity to the fluid source, comprising bedding-inclined zebra textures, boxwork textures and dolomite breccias that have been affected by recrystallization. Petrographical and geochemical evidence suggests that these rock textures were initiated due to dilatational fracturing, brecciation and precipitation of saddle dolomite as a cement, but significant recrystallization occurred during the later stages of dolomitization. These rock textures are closely associated with faults and carbonate-hosted ore deposits (e.g. magnesite, rare earth element and Mississippi Valley–type mineralization), thus providing invaluable information regarding fluid flux and carbonate metasomatism under elevated P/T conditions.Item Mapping amorphous SiO2 in Devonian shales and the possible link to marine productivity during incipient forest diversification(2023) Corlett, Hilary; Feng, Jilu; Playter, Tiffany; Rivard, BenoitSilica cycling in the world’s oceans is not straightforward to evaluate on a geological time scale. With the rise of radiolarians and sponges from the early Cambrian onward, silica can have two depositional origins, continental weathering, and biogenic silica. It is critical to have a reliable method of differentiating amorphous silica and crystalline silica to truly understand biogeochemical and inorganic silica cycling. In this study, opal-A is mapped across the Western Canada Sedimentary Basin in the Late Devonian Duvernay Formation shales using longwave hyperspectral imaging alongside geochemical proxies that differentiate between crystalline and amorphous SiO2, during the expansion of the world’s early forests. Signaled by several carbon isotope excursions in the Frasnian, the punctata Event corresponds to the expansion of forests when vascular land plants develop seeds and deeper root networks, likely resulting in increased pedogenesis. Nutrients from thicker soil horizons entering the marine realm are linked to higher levels of primary productivity in oceans and subsequent oxygen starvation in deeper waters at this time. The results of this study reveal, for the first time, the spatial distribution of amorphous SiO2 across a sedimentary basin during this major shift in the terrestrial realm when forests expand and develop deeper root networks.Item Far-ultraviolet dust extinction and molecular hydrogen in the diffuse Milky Way interstellar medium(2023) Putte, Dries Van De; Cartledge, Stefan; Gordon, Karl; Geoffrey, Chiekwero; Roman-Duval, JuliaWe aim to compare variations in the full-UV dust extinction curve (912–3000 Å), with the H I/H2/total H content along diffuse Milky Way sightlines, to investigate possible connections between ISM conditions and dust properties. We combine an existing sample of 75 UV extinction curves based on IUE and FUSE data, with atomic and molecular column densities measured through UV absorption. The H2 column density data are based on existing Lyman–Werner absorption band models from earlier work on the extinction curves. Literature values for the H I column density were compiled, and improved for 23 stars by fitting a Lyα profile to archived spectra. We discover a strong correlation between the H2 column and the far-UV extinction, and the underlying cause is a linear relationship between H2 and the strength of the far-UV rise feature. This extinction does not scale with H I, and the total H column scales best with A(V) instead. The carrier of the far-UV rise therefore coincides with molecular gas, and further connections are shown by comparing the UV extinction features to the molecular fraction. Variations in the gas-to-extinction ratio N (H) A(V) correlate with the UV-to-optical extinction ratio, and we speculate this could be due to coagulation or shattering effects. Based on the H2 temperature, the strongest far-UV rise strengths are found to appear in colder and denser sightlines.