Preparation, spectroscopic and structural characterization of η1-N and η2-Se,Se′ complexes of a P2N4Se2 ring

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dc.contributor.authorChivers, Tristram
dc.contributor.authorDoxsee, Daniel D.
dc.contributor.authorHilts, Robert
dc.contributor.authorMeetsma, Auke
dc.contributor.authorParvez, Masood
dc.contributor.authorGrampel, Johan C. van de
dc.date.accessioned2022-05-27T01:13:55Z
dc.date.available2022-05-27T01:13:55Z
dc.date.issued1992
dc.description.abstractThe reaction of 1,5-Ph4P2N4Se2, 1, prepared by the treatment of Ph2PN2(SiMe3)3 with a mixture of SeCl4 and Se2Cl2 in acetonitrile, with [PtCl2(PEt3)]2 gives the adducts [PtCl2(PEt3)]n[η1-N-Ph4P2N4Se2](2, n- 1; 3, n- 2) in which the P2N4Se2 ring is shown by an X-ray structural determination of 3 to contain a transannular Se–Se interaction; the oxidative addition of 1 or 2 to Pt(C2H4)(PPh3)2 produces the corresponding η2-Se,Se′ complexes.
dc.description.urihttp://library.macewan.ca/cgi-bin/SFX/url.pl/7OY
dc.identifier.urihttps://hdl.handle.net/20.500.14078/314
dc.languageEnglish
dc.language.isoen
dc.rightsAll Rights Reserved
dc.subjectx-ray structure
dc.subjectcrystal-structures
dc.subjectSe4N4
dc.titlePreparation, spectroscopic and structural characterization of η1-N and η2-Se,Se′ complexes of a P2N4Se2 ring
dc.typeArticle
dspace.entity.type
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