Preparation, spectroscopic and structural characterization of η1-N and η2-Se,Se′ complexes of a P2N4Se2 ring
| dc.contributor.author | Chivers, Tristram | |
| dc.contributor.author | Doxsee, Daniel D. | |
| dc.contributor.author | Hilts, Robert | |
| dc.contributor.author | Meetsma, Auke | |
| dc.contributor.author | Parvez, Masood | |
| dc.contributor.author | Grampel, Johan C. van de | |
| dc.date.accessioned | 2022-05-27T01:13:55Z | |
| dc.date.available | 2022-05-27T01:13:55Z | |
| dc.date.issued | 1992 | |
| dc.description.abstract | The reaction of 1,5-Ph4P2N4Se2, 1, prepared by the treatment of Ph2PN2(SiMe3)3 with a mixture of SeCl4 and Se2Cl2 in acetonitrile, with [PtCl2(PEt3)]2 gives the adducts [PtCl2(PEt3)]n[η1-N-Ph4P2N4Se2](2, n- 1; 3, n- 2) in which the P2N4Se2 ring is shown by an X-ray structural determination of 3 to contain a transannular Se–Se interaction; the oxidative addition of 1 or 2 to Pt(C2H4)(PPh3)2 produces the corresponding η2-Se,Se′ complexes. | |
| dc.description.uri | http://library.macewan.ca/cgi-bin/SFX/url.pl/7OY | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14078/314 | |
| dc.language | English | |
| dc.language.iso | en | |
| dc.rights | All Rights Reserved | |
| dc.subject | x-ray structure | |
| dc.subject | crystal-structures | |
| dc.subject | Se4N4 | |
| dc.title | Preparation, spectroscopic and structural characterization of η1-N and η2-Se,Se′ complexes of a P2N4Se2 ring | en |
| dc.type | Article | |
| dspace.entity.type |