Reactivity of coordinated [Ph2PCHP(S)Ph2]- and [Ph2P(S)CHP(S)Ph2]-: two-center, regiospecific reactivity in rhodium and iridium complexes and formation of a disubstituted methylene bridge between platinum atoms
| dc.contributor.author | Browning, Jane | |
| dc.contributor.author | Dixon, Keith R. | |
| dc.contributor.author | Hilts, Robert | |
| dc.date.accessioned | 2017-07-05 | |
| dc.date.accessioned | 2022-05-27T01:13:57Z | |
| dc.date.available | 2022-05-27T01:13:57Z | |
| dc.date.issued | 1988 | |
| dc.description.abstract | Reaction of methyl iodide with [Ir(Ph,P(S)-CHP(S)Ph,](cod)] occurs in a regiospecific sequence to form first [Ir{Ph,P(S)CHMeP(S)Ph,](cod)] I and only subsequently [IrMeI(Ph,P(S)CHMeP(S)Ph,](cod)] I. For [Rh-(Ph,PCHP(S)Ph,](cod)] the addition sequence is reversed. [Pt(Ph,P(S)CHP(S)Ph,)(MeOcod)] shows both ligand and metal site reactivity in transforming a novel dimer, [Pt,{Ph,P(S)CP(S)Ph,)(MeOcod),] , containing a quaternary carbon bridge between two platinum centers. The bridging carbon is part of four-member C,S chelate rings at both platinums. | |
| dc.description.uri | http://library.macewan.ca/cgi-bin/SFX/url.pl/7P5 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14078/323 | |
| dc.language | English | |
| dc.language.iso | en | |
| dc.rights | All Rights Reserved | |
| dc.subject | inorganic and nuclear chemistry | |
| dc.subject | organic chemistry | |
| dc.title | Reactivity of coordinated [Ph2PCHP(S)Ph2]- and [Ph2P(S)CHP(S)Ph2]-: two-center, regiospecific reactivity in rhodium and iridium complexes and formation of a disubstituted methylene bridge between platinum atoms | en |
| dc.type | Article | |
| dspace.entity.type |