Reactivity of coordinated [Ph2PCHP(S)Ph2]- and [Ph2P(S)CHP(S)Ph2]-: two-center, regiospecific reactivity in rhodium and iridium complexes and formation of a disubstituted methylene bridge between platinum atoms

dc.contributor.authorBrowning, Jane
dc.contributor.authorDixon, Keith
dc.contributor.authorHilts, Robert
dc.date.accessioned2017-07-05
dc.date.accessioned2022-05-27T01:13:57Z
dc.date.available2022-05-27T01:13:57Z
dc.date.issued1988
dc.description.abstractReaction of methyl iodide with [Ir(Ph,P(S)-CHP(S)Ph,](cod)] occurs in a regiospecific sequence to form first [Ir{Ph,P(S)CHMeP(S)Ph,](cod)] I and only subsequently [IrMeI(Ph,P(S)CHMeP(S)Ph,](cod)] I. For [Rh-(Ph,PCHP(S)Ph,](cod)] the addition sequence is reversed. [Pt(Ph,P(S)CHP(S)Ph,)(MeOcod)] shows both ligand and metal site reactivity in transforming a novel dimer, [Pt,{Ph,P(S)CP(S)Ph,)(MeOcod),] , containing a quaternary carbon bridge between two platinum centers. The bridging carbon is part of four-member C,S chelate rings at both platinums.
dc.description.urihttp://library.macewan.ca/cgi-bin/SFX/url.pl/7P5
dc.identifier.urihttps://hdl.handle.net/20.500.14078/323
dc.languageEnglish
dc.language.isoen
dc.rightsAll Rights Reserved
dc.subjectinorganic and nuclear chemistry
dc.subjectorganic chemistry
dc.titleReactivity of coordinated [Ph2PCHP(S)Ph2]- and [Ph2P(S)CHP(S)Ph2]-: two-center, regiospecific reactivity in rhodium and iridium complexes and formation of a disubstituted methylene bridge between platinum atoms
dc.typeArticle
dspace.entity.type
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