Solid state and solution structures of dimeric organolithium derivatives of a P2N4S2 ring

Author
Chivers, Tristram
Edwards, Mark
Hilts, Robert
Parvez, Masood
Vollmerhaus, Rainer
Faculty Advisor
Date
1993
Keywords
Abstract (summary)
An X-ray structural determination of the dimer [Li(Ph4P2N4S2Ph)-THFl2 (THF = tetrahydrofuran) reveals a step-shaped structure; 7Li and 31P NMR investigations of [Li(Ph4P2N4S2R)-THFl2 (R = Me, But, Ph), as a function of temperature and concentration, in THF solution show that this dimer is fluxional and indicate the presence of a second dimeric species.
Publication Information
Chivers, T., Edwards, M., Hilts, R., Parvez, M., & Vollmerhaus, R. (1993). Solid-State and Solution Structures of Dimeric Organolithium Derivatives of a P2n4s2 Ring. Journal of the Chemical Society-Chemical Communications, 19, 1483–1485. https://doi.org/10.1039/C39930001483
DOI
Notes
Item Type
Article
Language
English
Rights
All Rights Reserved