Formation, x-ray structure, and deprotonation of an S,S'-methylene-bridged P2N4S2 ring
| dc.contributor.author | Chivers, Tristram | |
| dc.contributor.author | Cowie, Martin | |
| dc.contributor.author | Edwards, Mark | |
| dc.contributor.author | Hilts, Robert | |
| dc.date.accessioned | 2022-05-27T01:13:58Z | |
| dc.date.available | 2022-05-27T01:13:58Z | |
| dc.date.issued | 1992 | |
| dc.description.abstract | There is an extensive chemistry of binary sulfur-nitrogen (S- N) anions, several of which are shown only in coordination complexes with metals. Although there is polarographic evidence for the formation of S4N4(2-) at low temperatures, this dianion has only been characterized in Ira and Pt5b complexes as a tridentate (N,S,S’) ligand formed by insertion of the metal into an S-N bond of S4N4. Anions of diphosphadithiatetrazocines 1 are unknown, but Pt0 or Pd0 compounds readily undergo oxidative addition with these norganic heterocycles to give ŋ2- S4ZS1-metal complexes.(6) | |
| dc.description.uri | https://library.macewan.ca/cgi-bin/SFX/url.pl/7PE | |
| dc.identifier.citation | Chivers, T., Cowie, M., Edwards, M. & Hilts, R. W. (1992). Formation, X-Ray Structure, and Deprotonation of an S,S’-Methylene-Bridged P2n4s2 Ring. Inorganic Chemistry, 31(16), 3349–3350. https://doi.org/10.1021/ic00042a005 | |
| dc.identifier.doi | https://doi.org/10.1021/ic00042a005 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14078/327 | |
| dc.language | English | |
| dc.language.iso | en | |
| dc.rights | All Rights Reserved | |
| dc.subject | sulfur nitrogen ligands | |
| dc.subject | complexes | |
| dc.subject | disulfides | |
| dc.subject | anions | |
| dc.subject | inorganic and nuclear chemistry | |
| dc.title | Formation, x-ray structure, and deprotonation of an S,S'-methylene-bridged P2N4S2 ring | en |
| dc.type | Article |