Preliminary communication: preparation and structure of a ruthenium dicarbonyl derivative of the P2N4S2 ring
| dc.contributor.author | Chivers, Tristram | |
| dc.contributor.author | Hilts, Robert | |
| dc.contributor.author | Parvez, Masood | |
| dc.date.accessioned | 2022-05-27T01:14:01Z | |
| dc.date.available | 2022-05-27T01:14:01Z | |
| dc.date.issued | 1994 | |
| dc.description.abstract | The reaction of Ru(CO)4(C2H4) or Ru(CO)5 with 1,5-Ph4P2N4S2 in CH2Cl2/hexane at 23°C produces the dimer [Ru(CO)2(Ph4 P2N4S2)]2 (2), which was shown by X-ray crystallography to have a centrosymmetric structure in which the P2N4S2 ring is attached to one ruthenium atom through two (geminal) nitrogen atoms and the remote sulfur atom and serves as a bridge to the other ruthenium atom via the second sulfur atom. Crystals of 2 ·2(CH2Cl2) are triclinic, space group P (No. 2), a = 12.901(1) Å, b = 13.072(1) Å, c = 10.123(1) Å, α = 100.88(1)°, β = 98.90(1)°, γ = 67.50(1)°, V = 1542.4(3) Å, Z = 1 with final R and Rw values of 0.040 and 0.027, respectively. | |
| dc.description.uri | https://library.macewan.ca/cgi-bin/SFX/url.pl/7Q6 | |
| dc.identifier.citation | Chivers, T., Hilts, R. W. & Parvez, M. (1994). Preliminary communication: Preparation and structure of a ruthenium dicarbonyl derivative of the P 2N 4S 2 ring. Journal of Organometallic Chemistry, 480(1), c4–c6. https://doi.org/10.1016/0022-328X(94)87129-9 | |
| dc.identifier.doi | https://doi.org/10.1016/0022-328X(94)87129-9 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14078/346 | |
| dc.language | English | |
| dc.language.iso | en | |
| dc.rights | All Rights Reserved | |
| dc.subject | Carbonyl | |
| dc.subject | Nitrogen | |
| dc.subject | Sulfur | |
| dc.subject | Ruthenium | |
| dc.title | Preliminary communication: preparation and structure of a ruthenium dicarbonyl derivative of the P2N4S2 ring | en |
| dc.type | Article |